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Details
The allyl side-chain protection can be removed selectively using e.g. Pd(PPh₃)₄ in the presence of N-methylmorpholine allowing on-resin modification of the γ-carboxyl group. Due to the lack of steric hindrance of the allyl group, prolonged treatment with harsher Fmoc cleavage agents or even piperidine may induce side-reactions.
Catalog Number
B-3255
Synonyms
Fmoc-Glu(OAll)-OH
Molecular Formula
C₂₃H₂₃NO₆
Relative Molecular Mass
409.44
CAS Registry Number
[133464-46-7]
Storage Conditions
-20 ± 5 °C
Links / Documents:
Bachem product citations
Product citations
M.Mergler et al.,
Proceedings of the 3rd International Peptide Symposium in conjunction with the 28th European Peptide Symposium, Prague 2004, p. 343, Kenes International, Geneva,
(2005)