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4025419

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Fmoc-Glu(2-phenylisopropyl ester)-OH

4025419

Product No. Pack Size Available ADS InfoAnalytical Data Sheet Unit Price Online Order Price Qty
4025419.0001 1 g Ships within 1 business day ADSExemplary Data Sheet of a current available lot.
CHF 194.00
CHF 180.42 (7%)
4025419.0005 5 g Ships within 1 business day ADSExemplary Data Sheet of a current available lot.
CHF 775.00
CHF 720.75 (7%)
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Details

Glu-derivative for the selective modification of the γ-carboxyl group. The OPp group can be removed selectively in the presence of Boc/OtBu with 1% TFA/DCM. Ocampo et al. applied OPp protection during the synthesis of a peptide-oligonucleotide conjugate and cleaved it with 3% trichloroacetic acid in DCM. Tofteng et al. generated a backbone pyroglutamyl imide moiety from C-terminal Glu after selective on-resin OPp removal.
Catalog Number B-2500
Synonyms Fmoc-Glu(OPp)-OH, Fmoc-Glu(O-2-PhiPr)-OH
Molecular Formula C₂₉H₂₉NO₆
Relative Molecular Mass 487.55
CAS Registry Number [200616-39-3]
Storage Conditions -20 ± 5 °C
Links / Documents:
Brochures:

Bachem product citations

L.Duma et al., J. Mol. Biol., 365, 1063 (2007)

Product citations

A.P.Tofteng et al., Angew. Chem. Int. Ed. Engl., 48, 7411 (2009)
S.M.Ocampo et al., Org. Lett., 7, 4349 (2005)
F.Dick et al., Peptides 1996, Proceedings of the 24th European Peptide Symposium, Edinburgh, Scotland, p. 339, R.Ramage and R.Epton, eds., Mayflower Scientific Ltd., England, (1998)