Q-1980
BOP
Benzotriazol-1-yloxy-tris(dimethylamino)-phosphonium hexafluorophosphate
| C12H22N6OP · PF6 | Mr: 442.28 | [56602-33-6] |
| Longterm storage temperature: | +5 ± 3 °C | C12H22N6OP · PF6 |
Coupling reagent for peptide synthesis, which suppresses enantiomerization. Useful reagent for lactonization, selective esterification or amidation of α-amino acids without racemization.
Literature:
B.Castro et al., Tetrahedron Lett., 14, 1219 (1975)
B.Castro et al., Synthesis, 413 (1977)
J.-A.Fehrentz and B.Castro, Synthesis, 676 (1983)
A.Wahhab and J.Leban, Tetrahedron Lett., 40, 235 (1999)
B.Castro et al., Tetrahedron Lett., 14, 1219 (1975)
B.Castro et al., Synthesis, 413 (1977)
J.-A.Fehrentz and B.Castro, Synthesis, 676 (1983)
A.Wahhab and J.Leban, Tetrahedron Lett., 40, 235 (1999)
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