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Fmoc-Asp(2-phenylisopropyl ester)-OH

B-2475

Product No. Pack Size Available ADS InfoAnalytical Data Sheet Unit Price Online Order Price Qty
B-2475.0001 1 g Ships within 1 business day ADSExemplary Data Sheet of a current available lot.
CHF 190.00
CHF 176.70 (7%)
B-2475.0005 5 g Ships within 1 business day ADSExemplary Data Sheet of a current available lot.
CHF 760.00
CHF 706.80 (7%)
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Details

An aspartic acid derivative allowing specific side chain deprotection with 1% TFA in dichloromethane. Ocampo et al. applied OPp protection during the synthesis of a peptide-oligonucleotide conjugate and cleaved it with 3% trichloroacetic acid in DCM.
The OPp derivative is far less prone towards base-catalyzed aspartimide formation than the OAll, OBzl, or ODmab esters, its stability comes close to the stability of the OtBu ester.
Item Number 4019087
Synonyms Fmoc-Asp(OPp)-OH, Fmoc-Asp(O-2-PhiPr)-OH
Molecular Formula C₂₈H₂₇NO₆
Relative Molecular Mass 473.53
CAS Registry Number [200336-86-3]
Storage Conditions -20 ± 5 °C

Product citations

F.Dick et al., Peptides 1996, Proceedings of the 24th European Peptide Symposium, Edinburgh, Scotland, p. 339, R.Ramage and R.Epton, eds., Mayflower Scientific Ltd., England, (1998)
C.Yue et al., Tetrahedron Lett., 34, 323 (1993)